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Answer (1 of 6) Chapter 574 when Ace died and made his first appearance in chapter 5, which was when Luffy woke up and went on a rampage after Law's surgery and after he lost Ace in Marineford He and Jinbe got into a tussle, Jinbe pinned Luffy down to chill him out, and Luffy flashed back toEp 663 Luffy discovers an unexpected face from his past in Dress Rosa!
